Solid state transformation of the crystalline monohydrate (CH3NH3)PbI3(H2O) to the (CH3NH3)PbI3 perovskite.
نویسندگان
چکیده
Colorless crystals of (CH3NH3·H2O)PbI3 spontaneously lose water at 298 K which triggers a transformation to the black (CH3NH3)PbI3 perovskite in the solid state as a porous microcrystalline solid with nanoscale substructure, but the dihydrate (CH3NH3)4PbI6·2H2O) requires much more forcing conditions to produce (CH3NH3)PbI3.
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ورودعنوان ژورنال:
- Chemical communications
دوره 51 56 شماره
صفحات -
تاریخ انتشار 2015